That’s due to absorption of certain parts of the sun’s light due to the atmosphere. When the sun is on the horizon (setting or rising) it goes through more atmosphere and that absorbs the blue light, leaving it look very red.
There are a number of reasons… light get bent and scattered by different things, and the different colours get bent and scattered differently.
The gas in the atmosphere itself, dust, water vapour, temperature changes, these all affect the path of light. This means some of the light gets to our eyes and some goes elsewhere…
In general that’s why the sky is blue, it’s why the sky can by red sometimes, it’s why the sun changes colour.
It is to do with the sun setting and the changes in the sun in relation to the atmosphere. Where the sun is at in the sky means that it is in a different area of the atmosphere. SO when we see it above us, it is in a different bit to when it is setting or rising 🙂
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